EVA: Polyethylene-co-vinyl acetate


Short Name
EVA
Name
Polyethylene-co-vinyl acetate
Group
CTP - Commodity Thermoplastics
General Properties
Chemical Formula
(C2H4)n(C4H6O2)m
Structural Formula

Properties

Glass Transition Temperature
-40 to +20 °C
Melting Temperature
30 to 110 °C
Melting Enthalpy
10 to 100 J/g
Decomposition Temperature
345 to 360 / 470 to 480 °C
Young's Modulus
7 to 120 MPa
Coefficient of Linear Thermal Expansion
160 to 200 *10¯6/K
Specific Heat Capacity
2.3 J/(g*K)
Thermal Conductivity
0.35 W/(m*K)
Density
0.92 to 0.95 g/cm³
Morphology
Semi-crystalline thermoplastic
General properties
High flexibility and toughness, good aging stability, high weather resistance, high gloss.
Processing
Injection moulding
Applications
Textile industry, hot melt adhesive, photovoltaic (embedding agent), agriculture and horticulture (films), cling films, shrink wrappings, shoe soles (VA-amount > 30 %)

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
10.65 mg
Isothermal Phase
8 min
Heating/Colling Rates
10 K/min
Crucible
Al, piercec
Atmosphere
N2 (50 ml/min)

Evaluation

In the above graphics, only the 1st heating (blue) was evaluated since the effects in the 2nd heating − after controlled cooling – are no longer resolved.
In the 1st heating (blue curve), the glass transition occurs at -23°C (midpoint, with a change in specific heat of 0.56 J/(g·K)). It is followed by two overlapping, endothermal melting effects at 51°C and 87°C (peak temperatures). The entire heat of fusion of the combined peaks amounts to approx. 75 J/g.

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