PIB: Polyisobutylene


Short Name
PIB
Name
Polyisobutylene
Group
CTP - Commodity Thermoplastics
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
-70 to -60 °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
390 to 400 °C
Young's Modulus
- MPa
Coefficient of Linear Thermal Expansion
120 *10¯6/K
Specific Heat Capacity
1.97 J/(g*K)
Thermal Conductivity
0.12 to 0.20 W/(m*K)
Density
0.91 to 0.93 g/cm³
Morphology
Amorphous thermoplastic
General properties
High elongation at break, good electrical insulating properties, resistant to acids, bases and salts.
Processing
Extrusion, calendering.
Applications
Building industry, sealing compounds, component of coatings, adhesive, basic material for chewing gum, plastification of explosives.

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
15.17 mg
Isothermal Phase
20 min/2 min/20 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (40 ml/min)

Evaluation

PIB is an amorphous thermoplastic, as reflected in the DSC curves. In both heatings, a glass transition at -64°C (midpoint) was observed exclusively. The step heights (Δcp) are identical in both curves and have a value of 0.39 J/(g·K) in both the 1st heating (blue) and 2nd heating (green).

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