PVC-U: Polyvinylchloride (without plasticizer)


Short Name
PVC-U
Name
Polyvinylchloride (without plasticizer)
Group
CTP - Commodity Thermoplastics
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
80 to 90 °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
285 to 315 / 460 to 475 °C
Young's Modulus
2700 to 3000 MPa
Coefficient of Linear Thermal Expansion
60 to 80 *10¯6/K
Specific Heat Capacity
0.84 to 1.17 J/(g*K)
Thermal Conductivity
0.13 to 0.29 W/(m*K)
Density
1.38 to 1.55 g/cm³
Morphology
Amorphous thermoplastic
General properties
High mechanical stability, stiffness and hardness, good chemical resistance, good electrical and insulating properties, low tendency to stress cracking, good weatherability, low humidity absorption.
Processing
Extrusion, inject moulding, blow moulding, calendering, chip removing process.
Applications
Building industry (e.g. window profiles (with stabilizers), pipes), mechanical and apparatus engineering, electrical engineering, packaging industry.

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
10.82 mg
Isothermal Phase
5 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (40 ml/min)

Evaluation

Due to the missing plasticizer the glass transition of the entirely amorphous plastic PVC-U occurred at much higher temperatures, compared to PVC-P; in the present case at approx. 84°C (in both heatings, midpoint) with a step height (Δcp) of 0.32 J/(g·K) in the 2nd heating. The slight waves, overlapping the glass transition step in the 1st heating, are probably due to stress in the material that is dissipated during thermal treatment.

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