SAN: Styrene-acrylonitrile copolymer


Short Name
SAN
Name
Styrene-acrylonitrile copolymer
Group
CTP - Commodity Thermoplastics
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
95 to 110/(125) °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
415 to 425 °C
Young's Modulus
3500 to 3700 MPa
Coefficient of Linear Thermal Expansion
60 to 80 *10¯6/K
Specific Heat Capacity
1.18 to 1.20 J/(g*K)
Thermal Conductivity
0.15 to 0.17 W/(m*K)
Density
1.08 g/cm³
Morphology
Amorphous thermoplastic
General properties
High transparency, chemical resistance, high strength, high surface hardness, high scratch resistance.
Processing
Extrusion, injection moulding, thermoforming.
Applications
Transparent household goods, cosmetics packaging, medical components.

Internet Links

Wikipedia: http://en.wikipedia.org/wiki/Styrene-acrylonitrile_resin

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
11.79 mg
Isothermal Phase
5 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (50 ml/min)

Evaluation

As an entirely amorphous thermoplastic, SAN has a glass transition in this case at 109°C (both heatings, midpoint each) with a step height (Δcp) of 0.40 J/(g.K) and 0.41 J/(g.K), respectively.
In the 2nd heating (green), the glass step shows a relaxation peak, indicating that short-range orders have formed in the polymer during the controlled cooling at 10 K/min. The thermomechanical history of the sample can be noticed in the DSC curve of the 1st heating (blue) by means of some slight waves.

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