NETZSCH Measurements
- Instrument
-
DSC 204 F1 Phoenix®
- Sample Mass
- 10.68 mg
- Isothermal Phase
- 5 min
- Heating/Colling Rates
- 10 K/min
- Crucible
- Al, pierced
- Atmosphere
- N2 (50 ml/min)
Evaluation
In this example, an endothermal melting effect was observed with a peak temperature of 292°C (2nd heating, green) and an enthalpy of 91 J/g. The midpoint temperature of 58°C of the glass transition in the 1st heating (blue) increased to 74°C in the 2nd heating (green) as a result of water evaporation (small peak at 129°C with an enthalpy of 0.6 J/g) during the 1st heating.
The shoulder at around 240°C prior to the main melting peak in the 1st heating is due to the thermomechanical history of the sample since it was absent in the 2nd heating.