NETZSCH Measurements
- Instrument
-
DSC 204 F1 Phoenix®
- Sample Mass
- 10.73 mg
- Isothermal Phase
- 5 min
- Heating/Colling Rates
- 10 K/min
- Crucible
- Al, pierced
- Atmosphere
- N2 (50 ml/min)
Evaluation
The as-received PA6 granulate was highly amorphous, as demonstrated in the 1st heating (blue) by a glass transition with a high Δcp (0.16 J/(g.K) at 36°C) and post-crystallization at 190°C. In the temperature range between approx. 70°C and 150°C, a broad, flat peak can be seen, probably due to evaporation of water, which is responsible for the positive shift in the glass transition temperature of around 15 K between the 1st and 2nd heating.
After controlled cooling, a multiple structured melting peak, indicating several melting phases, was observed in the 2nd heating (green). The temperature of the main peak occurred at 223°C, within the range typical for PA6.