NETZSCH Measurements
- Instrument
-
DSC 204 F1 Phoenix®
- Sample Mass
- 10.15 mg
- Isothermal Phase
- 5 min
- Heating/Colling Rates
- 10 K/min
- Crucible
- Al, pierced
- Atmosphere
- N2 (50 ml/min)
Evaluation
As a semi-crystalline thermoplastic, PA6.6 showed a glass transition at 68°C (midpoint) in the 2nd heating (green) and an endothermal melting range from approx. 200°C to 270°C. As is often the case for PA6.6, a second melting transition at 250°C can be observed as a pre-peak (or shoulder) prior to the actual main melting effect with a peak temperature of 261°C. In the 1st heating (blue), post-crystallization (exothermal effect at 237°C) occurred prior to the melting peak.
The corresponding glass transition temperature in the 1st heating at 54°C (midpoint) is lower than the Tg at 68°C in the 2nd heating due to the presence of a small amount of water, as evidenced by the shallow evaporation peak between 100°C and 200°C (blue curve).