PBT: Polybutylene terephthalate


Short Name
PBT
Name
Polybutylene terephthalate
Group
ETP - Engineering Thermoplastics
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
40 to 60 °C
Melting Temperature
220 to 230 °C
Melting Enthalpy
142 J/g
Decomposition Temperature
400 to 420 °C
Young's Modulus
2500 to 2800 MPa
Coefficient of Linear Thermal Expansion
80 to 100 *10¯6/K
Specific Heat Capacity
1.3 J/(g*K)
Thermal Conductivity
0.25 to 0.29 W/(m*K)
Density
1.30 to 1.32 g/cm³
Morphology
Semi-crystalline thermoplastic
General properties
High stability and stiffness. Good chemical resistance to many solvents. High dimensional stability. Good friction and wear properties
Processing
Injection molding, extrusion
Applications
Electrical engineering/electronics. Vehicle manufacturing. Household goods

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
12.06 mg
Isothermal Phase
3 min/3 min/5 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (50 ml/min)

Evaluation

A glass transition (here at 42°C, midpoint) and a clearly structured endothermal melting effect for the α (peak temperature 226°C) and β phase (peak temperature 217°C) in the 2nd heating (green) are characteristic of PBT. In the 1st heating (blue), the glass transition midpoint temperature of 44°C was comparable to that in the 2nd heating, but is overlapped with a relaxation peak. Prior to the melting transition, a post crystallization (small exothermal peak at 207°C) occurred in the 1st heating.

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