ASA: Acrylonitrile-styrene- acrylate copolymer


Short Name
ASA
Name
Acrylonitrile-styrene- acrylate copolymer
Group
CTP - Commodity Thermoplastics
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
-50 to -40 / 95 to 105 °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
415 to 425 °C
Young's Modulus
2300 to 2900 MPa
Coefficient of Linear Thermal Expansion
85 to 105 *10¯6/K
Specific Heat Capacity
1.3 to 1.4 J/(g*K)
Thermal Conductivity
0.17 to 0.19 W/(m*K)
Density
1.04 to 1.07 g/cm³
Morphology
Amorphous thermoplastic
General properties
High impact strength and stability. High chemical stability, high gloss, high weatherability.
Processing
Injection molding,extrusion
Applications
Outer parts of vehicles. Thermalls stressed electrical devices, e.g.coffee machines and microwaves. Sport and leisure sector.

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
11.40 mg
Isothermal Phase
15 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (50 ml/min)

Evaluation

Two glass transitions can be seen in the above DSC curves. The first glass transition can be attributed to the acrylate component and occurs in the 2nd heating at -50°C (midpoint, green curve) with a change in specific heat of 0.04 J/(g.K)).
The second glass transition is due to the styrene component. The larger the relaxation peak, the more positively shifted the glass transition temperature to higher temperatures, as in this example.

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