PSU: Polysulfone


Short Name
PSU
Name
Polysulfone
Group
HTRTP - High-Temperature Resistant Thermoplastics
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
185 to 190 °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
530 to 540 °C
Young's Modulus
2500 to 2700 MPa
Coefficient of Linear Thermal Expansion
50 to 60 *10¯6/K
Specific Heat Capacity
1.37 J/(g*K)
Thermal Conductivity
0.15 W/(m*K)
Density
1.24 to 1.25 g/cm³
Morphology
Amorphous polymer
General properties
High stability and stiffness. Good toughness. Good chemical resistance. Low water absorption. Very good electrical insulation properties
Processing
Injection molding, extrusion for the production of thin films
Applications
Electrical engineering (e.g., condensators). Medical engineering. Food technology. Aerospace (helmets). Chemical and laboratory equipment

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
12.52 mg
Isothermal Phase
3 min/3 min/5 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (40 ml/min)

Evaluation

Since PSU is entirely amorphous, the DSC curves above show only one glass transition with a glass transition midpoint temperature at 187°C in the 2nd heating (green) and 188°C in the 1st heating (blue). The glass transition in the 2nd heating is overlapped by a larger relaxation peak than in the 1st heating. This indicates an increase in short-range order during the controlled cooling at 10 K/min than was originally present in the material.
The heights of the glass transition steps of 0.24 J/(g.K) (1st heating) and 0.25 J/(g.K) (2nd heating) are nearly identical.

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