NETZSCH Measurements
- Instrument
-
DSC 204 F1 Phoenix®
- Sample Mass
- 12.52 mg
- Isothermal Phase
- 3 min/3 min/5 min
- Heating/Colling Rates
- 10 K/min
- Crucible
- Al, pierced
- Atmosphere
- N2 (40 ml/min)
Evaluation
Since PSU is entirely amorphous, the DSC curves above show only one glass transition with a glass transition midpoint temperature at 187°C in the 2nd heating (green) and 188°C in the 1st heating (blue). The glass transition in the 2nd heating is overlapped by a larger relaxation peak than in the 1st heating. This indicates an increase in short-range order during the controlled cooling at 10 K/min than was originally present in the material.
The heights of the glass transition steps of 0.24 J/(g.K) (1st heating) and 0.25 J/(g.K) (2nd heating) are nearly identical.