NETZSCH Measurements
- Instrument
-
DSC 204 F1 Phoenix®
- Sample Mass
- 11.12 mg
- Isothermal Phase
- 5 min
- Heating/Colling Rates
- 10 K/min
- Crucible
- Al, pierced
- Atmosphere
- N2 (50 ml/min)
Evaluation
The present FEP sample shows an endothermal melting effect at 266°C (peak temperature, 2nd heating, green) in the temperature range between 0°C and 310°C with a melting enthalpy of 24 J/g.
The shift of the peak temperature of more than 2 K to lower values in the 2nd heating (266°C compared to 268°C in the 1st heating, blue) can be explained by a better contact between the sample and crucible bottom after the first melting. The melting peak in the 1st heating (blue) is a bit slimmer compared to the 2nd heating; this indicates a narrower distribution of crystallites.