FEP: Tetrafluoroethylene/hexafluoropropylene copolymer


Short Name
FEP
Name
Tetrafluoroethylene/hexafluoropropylene copolymer
Group
HTRTP - High-Temperature Resistant Thermoplastics
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
- °C
Melting Temperature
253 to 282 °C
Melting Enthalpy
- J/g
Decomposition Temperature
510 to 600 °C
Young's Modulus
350 MPa
Coefficient of Linear Thermal Expansion
80 *10¯6/K
Specific Heat Capacity
1.12 J/(g*K)
Thermal Conductivity
0.25 W/(m*K)
Density
2.12 to 2.17 g/cm³
Morphology
Semi-crystalline thermoplastic
General properties
Good chemical resistance. High impact strength. Smooth surface
Processing
Injection molding, extrusion
Applications
Heating cables, heating tapes. Electronics (e.g., wires, cables on the communication sector). Chemical industry (lining for valves, tubes, container). Solar cells (layer films)

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
11.12 mg
Isothermal Phase
5 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (50 ml/min)

Evaluation

The present FEP sample shows an endothermal melting effect at 266°C (peak temperature, 2nd heating, green) in the temperature range between 0°C and 310°C with a melting enthalpy of 24 J/g.
The shift of the peak temperature of more than 2 K to lower values in the 2nd heating (266°C compared to 268°C in the 1st heating, blue) can be explained by a better contact between the sample and crucible bottom after the first melting. The melting peak in the 1st heating (blue) is a bit slimmer compared to the 2nd heating; this indicates a narrower distribution of crystallites.

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