CR: Chloroprene rubber


Short Name
CR
Name
Chloroprene rubber
Group
EM - Elastomers
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
-45 to -30 °C
Melting Temperature
40 to 75 °C
Melting Enthalpy
1 to 10 J/g
Decomposition Temperature
365 to 380 / 445 to 460 °C
Young's Modulus
- MPa
Coefficient of Linear Thermal Expansion
185 to 250 *10¯6/K
Specific Heat Capacity
- J/(g*K)
Thermal Conductivity
0.18 to 0.20 W/(m*K)
Density
1.25 g/cm³
Morphology
Rubber
General properties
Good mechanical properties and elasticity. Good ozone, weather, chemical and aging resistance. High non-inflammability
Processing
Thermally with diamine, with hydroxyphenyl or a mixture of zinc and magnesium oxides or by reaction with ethylenethiourea
Applications
Technical rubber goods (e.g., seals, profiles). Automobile industry. Electrical industry. Textile industry. Adhesives, hoses, coatings

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
21.18 mg
Isothermal Phase
8 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (40 ml/min)

Evaluation

As an amorphous polymer, CR shows a glass transition at approx. -35°C (midpoint) in both heatings with a step height (Δcp) of 0.38 J/(g.K) in the 2nd heating (green).
The small endothermal effect at 45°C (peak temperature) in the 1st heating (blue) is probably due to the melting of an additive, which, in the molten state, dissolves in the elastomer matrix and is therefore no longer visible in the 2nd heating (green).

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