NETZSCH Measurements
- Instrument
-
DSC 204 F1 Phoenix®
- Sample Mass
- 24.79 mg
- Isothermal Phase
- 8 min
- Heating/Colling Rates
- 5 K/min
- Crucible
- High-pressure crucibles of steel, closed
- Atmosphere
- N2 (40 ml/min)
Evaluation
The above plot shows a DSC curve from a single heating of a melamine formaldehyde resin (MF).
The glass transition at approx. 61°C (midpoint) is overlapped by a large endothermal enthalpy relaxation peak (peak temperature 69°C) and is immediately followed by an exothermal curing with a peak temperature of approx. 136°C and a reaction
enthalpy of 48 J/g.
A temperature-modulated DSC (TM-DSC) measurement (not presented here) would be able to separate the reversing glass transition from the non-reversing endothermal relaxation and the exothermal reaction peaks.