MF: Melamine-formaldehyde resin


Short Name
MF
Name
Melamine-formaldehyde resin
Group
TS - Thermosets
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
70 to 130 °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
340 to 400 °C
Young's Modulus
6000 to 10000 MPa
Coefficient of Linear Thermal Expansion
40 to 60 *10¯6/K
Specific Heat Capacity
1.2 J/(g*K)
Thermal Conductivity
0.35 to 0.40 W/(m*K)
Density
1.48 to 1.50 g/cm³
Morphology
Thermoset
General properties
Good chemical resistance. High gloss. High surface hardness. High abrasion resistance. Good electrical insulating properties
Processing
Compression, injection molding, extrusion molding
Applications
Furniture industry (adhesive resin for, e.g., wood bonding, face veneer …). Electrical industry. Impregnation of textiles. Matrix for fiber-reinforced composites. Camping dishes, kitchen tools

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
24.79 mg
Isothermal Phase
8 min
Heating/Colling Rates
5 K/min
Crucible
High-pressure crucibles of steel, closed
Atmosphere
N2 (40 ml/min)

Evaluation

The above plot shows a DSC curve from a single heating of a melamine formaldehyde resin (MF).
The glass transition at approx. 61°C (midpoint) is overlapped by a large endothermal enthalpy relaxation peak (peak temperature 69°C) and is immediately followed by an exothermal curing with a peak temperature of approx. 136°C and a reaction
enthalpy of 48 J/g.
A temperature-modulated DSC (TM-DSC) measurement (not presented here) would be able to separate the reversing glass transition from the non-reversing endothermal relaxation and the exothermal reaction peaks.

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