PF: Phenol-formaldehyde resin


Short Name
PF
Name
Phenol-formaldehyde resin
Group
TS - Thermosets
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
70 to 120 °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
450 to 555 °C
Young's Modulus
5600 to 12000 MPa
Coefficient of Linear Thermal Expansion
15 to 50 *10¯6/K
Specific Heat Capacity
1.0 to 1.3 J/(g*K)
Thermal Conductivity
0.35 to 0.70 W/(m*K)
Density
1.40 to 1.80 g/cm³
Morphology
Thermoset
General properties
Very hard and stiff. Good chemical resistance. Low inflammability
Processing
Compression, injection molding, extrusion molding, transfer molding, foaming
Applications
Electrical industry (e.g., for circuit boards, plugs). Building industry (weather-resistant glue, for production of insulating materials). Vehicle construction. Matrix for fiber-reinforced composites

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
26.26 mg
Isothermal Phase
10 min
Heating/Colling Rates
5 K/min/10 K/min cooling/20 K/min
Crucible
High-pressure steel crucibles, closed
Atmosphere
N2 (40 ml/min)

Evaluation

The 1st heating (blue ) shows a glass transition at approx. 48°C (midpoint) with an overlapping enthalpy relaxation, followed by a multi-step exothermal curing effect with peak temperatures of 141°C and 206°C and a total enthalpy of 191 J/g. In the
following 2nd heating (green), the glass transition shifted to approx. 72°C (midpoint) as a result of the extensive curing in the previous heating step.

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