PUR: Polyurethane


Short Name
PUR
Name
Polyurethane
Group
TS - Thermosets
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
10 to 180 °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
240 to 350 °C
Young's Modulus
- MPa
Coefficient of Linear Thermal Expansion
130 to 200 *10¯6/K
Specific Heat Capacity
1.70 to 2.10 J/(g*K)
Thermal Conductivity
< 0.19 W/(m*K)
Density
1.10 to 1.70 g/cm³
Morphology
Thermoset
General properties
Depending on the composition – the stiffness range expands from soft rubbers to technical plastics. Good abrasion resistance
Processing
Injection molding, foaming, coating
Applications
Automotive industry. Furniture industry. Building industry. Sports and leisure. Shoe industry (soles). Polyurethane paints and coatings. Casting compounds. Matrix for composites

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
18.95 mg
Isothermal Phase
5 min
Heating/Colling Rates
10 K/min
Crucible
Al, pierced
Atmosphere
N2 (40 ml/min)

Evaluation

In the 1st heating, the glass transition at 107°C (midpoint) was followed by a broad, shallow, exothermal post-curing effect between approx. 120°C and 200°C (peak temperature 167°C). Due to the post-curing, the glass transition in the 2nd heating
(after controlled cooling) was approx. 4 K (midpoint temperature 111°C) higher.
The position of the glass transition temperature is directly related to the degree of curing.
The more extensive the post-curing, the more the glass transition shifts to higher temperatures.

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