UF: Urea-formaldehyde resin


Short Name
UF
Name
Urea-formaldehyde resin
Group
TS - Thermosets
General Properties
Chemical Formula
Structural Formula

Properties

Glass Transition Temperature
60 to 110 °C
Melting Temperature
- °C
Melting Enthalpy
- J/g
Decomposition Temperature
260 to 355 °C
Young's Modulus
7000 to 10500 MPa
Coefficient of Linear Thermal Expansion
40 to 60 *10¯6/K
Specific Heat Capacity
1.2 to 1.3 J/(g*K)
Thermal Conductivity
0.35 to 0.40 W/(m*K)
Density
1.5 g/cm³
Morphology
Thermoset
General properties
High strength. High scratch resistance. Very good electrical insulating properties. Light resistant
Processing
Compression, injection molding, transfer molding
Applications
Building industry (binder for plywood). Electrical industry (e.g., plugs, light switches). Sanitary area (e.g., toilet seats). Caps for cosmetics

Internet Links

NETZSCH Measurements

Instrument
DSC 204 F1 Phoenix®
Sample Mass
24.04 mg
Isothermal Phase
8 min
Heating/Colling Rates
5 K/min heating/10 K/min cooling
Crucible
High-pressure steel crucibles, closed
Atmosphere
N2 (40 ml/min)

Evaluation

In the 1st heating (blue), a glass transition occurred at 45°C (midpoint), overlapped by a small endothermal relaxation effect which is followed by a broad exothermal reaction peak due to the curing reaction (peak temperature 128°C, reaction enthalpy 53 J/g). After controlled cooling, only a glass transition with a midpoint temperature of 104°C and a step height (Δcp) of 0.14 J/(g·K) can be seen in the 2nd heating (green). This Tg is also overlapped by a relaxation effect.
By means of TM-DSC (temperature-modulated DSC), it is possible to separate the glass transition from the relaxation endotherm and the curing exotherm.

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