NETZSCH Measurements
- Instrument
-
DSC 204 F1 Phoenix®
- Sample Mass
- 24.04 mg
- Isothermal Phase
- 8 min
- Heating/Colling Rates
- 5 K/min heating/10 K/min cooling
- Crucible
- High-pressure steel crucibles, closed
- Atmosphere
- N2 (40 ml/min)
Evaluation
In the 1st heating (blue), a glass transition occurred at 45°C (midpoint), overlapped by a small endothermal relaxation effect which is followed by a broad exothermal reaction peak due to the curing reaction (peak temperature 128°C, reaction enthalpy 53 J/g). After controlled cooling, only a glass transition with a midpoint temperature of 104°C and a step height (Δcp) of 0.14 J/(g·K) can be seen in the 2nd heating (green). This Tg is also overlapped by a relaxation effect.
By means of TM-DSC (temperature-modulated DSC), it is possible to separate the glass transition from the relaxation endotherm and the curing exotherm.